Table 3.
Calculated relaxation parameters in TIP4P/Ew water at B = 9.4 T. R1, R2 in s−1, τm in ps.)
| 273K | 283K | 300K | 315K | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| C-H | S2 | τm | R1 | S2 | τm | R1 | S2 | τm | R1 | S2 | τm | R1 |
| C-H1g | 0.93 | 118 | 2.28 | 0.92 | 105 | 2.03 | 0.90 | 63 | 1.22 | 0.79 | 48 | 0.86 |
| C-H2g | 0.93 | 125 | 2.42 | 0.89 | 113 | 2.11 | 0.91 | 66 | 1.28 | 0.89 | 46 | 0.88 |
| C-H3g | 0.92 | 125 | 2.39 | 0.86 | 115 | 2.10 | 0.90 | 65 | 1.26 | 0.89 | 45 | 0.86 |
| C-H4g | 0.91 | 133 | 2.51 | 0.89 | 112 | 2.11 | 0.89 | 69 | 1.31 | 0.88 | 47 | 0.90 |
| C-H5g | 0.93 | 127 | 2.44 | 0.90 | 112 | 2.11 | 0.90 | 67 | 1.30 | 0.89 | 46 | 0.89 |
| C-H3f | 0.82 | 153 | 2.65 | 0.90 | 105 | 2.00 | 0.85 | 68 | 1.25 | 0.86 | 47 | 0.87 |
| C-H4f | 0.84 | 136 | 2.38 | 0.84 | 107 | 1.91 | 0.86 | 58 | 1.08 | 0.82 | 44 | 0.79 |
| C-H5f | 0.87 | 150 | 2.68 | 0.87 | 118 | 2.14 | 0.88 | 69 | 1.30 | 0.86 | 50 | 0.92 |
| C-H6g | 0.81 | 111 | 1.90 | 0.81 | 94 | 1.61 | 0.77 | 58 | 0.96 | 0.77 | 37 | 0.62 |
| C-H1f | 0.83 | 99 | 1.75 | 0.83 | 83 | 1.47 | 0.84 | 51 | 0.92 | 0.81 | 36 | 0.63 |
| C-H6f | 0.79 | 92 | 1.53 | 0.75 | 77 | 1.25 | 0.75 | 46 | 0.76 | 0.72 | 34 | 0.54 |