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. 2012 Jan 13;287(11):8515–8530. doi: 10.1074/jbc.M111.324012

TABLE 2.

¹H and ¹³C NMR chemical shifts (ppm) of the O-antigen of V. fischeri at 25 °C

Sugar residues	¹³C/¹H (ppm)
Sugar residues	1	2	3	4	5	6	7	8	9	NAc	NAc
A →8)-α-8eLeg5Ac7Ac-(2→	176.60	103.01	43.58	71.04	55.36	74.26	56.48	73.79	16.71	24.88^a	24.73^b
			2.75eq	3.51	3.67	3.98	3.89	3.89	1.31	1.92^a	2.03^b
			1.74ax							176.58^a	176.35^b
B →3)-α-d-GalNAc-(1→	95.38	50.73	79.37	71.34	73.27	63.31				24.94^c
	4.96	4.23	3.61	4.16	3.77	3.68				2.01^c
						3.73				176.95^c
C →3)-β-l-FucNAc-(1→	105.50	54.05	78.50	72.96	73.03	18.26				24.64^c
	4.38	3.95	3.78	3.72	3.77	1.24				1.95^c
										176.67^c
D →3)-β-l-FucNAc-(1→	101.24	50.60	76.25	73.59	69.15	18.55				24.78^c
	5.00	4.15	3.96	4.04	4.07	1.22				2.01^c
										176.90^c
E →4,8)-α-8eLeg5Ac7Ac-(2→	174.99	105.90	40.51	74.26	52.98	75.25	56.14	74.53	16.98	24.71^a	24.60^b
			2.79eq	3.56	3.79	4.11	3.95	3.82	1.39	1.88^a	1.96^b
			1.54ax							176.55^a	176.70^b
F α-Yer-(1→4)	95.68	66.92	32.16	77.59	69.83	14.87	71.78^d	17.90^e
	4.89	3.94	1.76eq		4.07	1.08	3.65^d	1.15^e
			1.70ax
G α-Yer-(1→8)	95.75	67.28	32.16	77.59	69.83	14.89	71.78^d	17.90^e
	4.91	3.93	1.76eq		4.07	1.11	3.65^d	1.15^e
			1.68ax

Minor form
A α-8eLeg5Ac7Ac-(2→	176.17	103.42	43.38	71.24	55.36	75.72	55.67	71.50	21.24	25.03^a	24.78^b
			2.77eq	3.51	3.64	3.94	3.90	4.06	1.22	1.92^a	2.01^b
			1.76ax							176.70^a	176.81^b

^a For 5NAc.

^b For 7NAc.

^c For 2NAc.

^d For the first position of the group attached to the 4th carbon on the sugar ring, i.e. 4¹ position or the —CHOH– group.

^e For the second position of the group attached to the 4th carbon on the sugar ring, i.e. 4² position or the CH₃– group.