. 2012 Apr;78(8):2706–2715. doi: 10.1128/AEM.07381-11

Table 5.

Absorption maxima^a of MCPs formed via dioxygenation of CBs by prototype hybrid BphAs and tentative assignments of initially oxidized carbons

CB chlorinated carbons	CB potentially oxidized carbons	Resulting MCP
		Chlorinated carbons^b	Expected λ_max (nm)^c^,^d	Previous experimental data		BphA_WB15h λ_max (nm)	BphA_WC18h λ_max (nm)
		Chlorinated carbons^b	Expected λ_max (nm)^c^,^d	λ_max (nm)	Oxidized carbons	BphA_WB15h λ_max (nm)	BphA_WC18h λ_max (nm)
2,2′	2,3	8	∼393	392^c	2,3^h	393	393
	5,6	5,8	∼393	395^e	5,6^e	393	393
2,4′	2,3	10	>430	438^c	2,3^h	433 (399)
	5,6	5,10	∼402				400
	2′,3′	3,8	∼393
3,4,2′	2,3	3,8	∼393
	5,6	3,4,8	∼393
	2′,3′	9,10	>430	440 (401)^f	2′,3′^h	435 (401)
	5′,6′	5,9,10	∼402				401
3,5,2′	2,3	4,8	∼393
	2′,3′	9,11	>430	435 (402)^f	2′,3′^h	435 (400)
	5′,6′	5,9,11	∼402				400
3,3′	2,3	9	>430			NPOⁱ
	5,6	4,9	∼410	430 (410)^c	5,6^e^,^h		395
	5,6	4,9	∼410	425 (395)^e	5,6^e^,^h		395
2,3,3′	5,6	4,5,9	∼402
	2′,3′	8,9	∼393			385 ± 3	388^j
	5′,6′	4,8,9	∼393	400 (370)^c	5′,6′^h	385 ± 3	388^j
2,4,3′	2,3	3,9	>430	433^f	2,3^f	420 (438)
	5,6	3,5,9	∼402	437^f	5,6^h
	2′,3′	8,10	∼393				388^j
	5′,6′	4,8,10	∼393				388^j
4,4′	2,3	3,10	>430	432^e^,^g	2,3^e^,^h	NPO	433

λ_max. All values are ±2 nm unless otherwise indicated. The numbers in parentheses indicate final values in case of a shift of the absorption maximum during incubations.

Carbon numbering in MCP is as shown here: Inline graphic .

Data from reference 33.

Data from reference 32.

Data from reference 9.

Standfuß-Gabisch and Hofer, unpublished.

Data from reference 43.

Data from reference 34.

ⁱ

NPO, no product observed.

Absorption unstable.