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. Author manuscript; available in PMC: 2013 Mar 19.
Published in final edited form as: Angew Chem Int Ed Engl. 2012 Feb 8;51(12):2907–2911. doi: 10.1002/anie.201109033

Figure 1.

Figure 1

(a) Peptide-catalyzed site-selective thiocarbonylation as a precursor to radical deoxygenation. (b) Thiocarbonylation of erythromycin A with N-methyl imidazole catalyst. (c) Thiocarbamate formation on 2′-acetyl erythromycin A.