Table 2.

Ni-Catalyzed Allylic Boronate Synthesis from Allylic Acetates.

entry	substrate	product	yield (%)a
1			92
2			84b
3			94
4			96
5			92
6			95
7			52d
8			70e
9			93c,e

^aIsolated yield of purified material. Value is an average of two experiments.

^bContains ca. 5% impurity.

^cEmployed 10% catalyst and PPh₃.

^dEmployed 10% catalyst.

^eProduct is a 2:1 ratio of E:Z isomers as established by NMR.