Table 3.

Scope of pyrrolidine synthesis.^[a]

Entry	Substrate	Product	Yield [%][b]	ee [%][c]
1	7a, R1 =Me, R2 =Ts	8a	81	88
2	7b, R1 =Me, R2 =Ms	8b	78	43
3	7c, R1 =Me, R2 =Ns	8c	80	60
4	7d, R1 =Ph, R2 =Ts	8d	85	93
5	7e, R1 =H, R2 =Ts	8e	77	73
6	7f, R1 =H, R2 =3,5-di-tBu-C6H3SO2	8f	85	88
7	7g	8g	78	92
8	9	10	78	83
9	11	12	74	16
10[d]	13	14	73	27

^[a]Reactions run as described in Table 1, entry 7 except reaction time was extended to 11h.

^[b]Yield of product isolated by flash chromatography on SiO₂.

^[c]Enantioselectivity determined by HPLC on a chiral stationary phase.

^[d]Ligand 2 was used.