Figure - PMC

Skip to main content

View full-text article in PMC

. Author manuscript; available in PMC: 2013 Feb 20.

Published in final edited form as: Inorg Chem. 2012 Feb 8;51(4):2086–2096. doi: 10.1021/ic2017819

(○), the K-edge XAS of 0.10 M Cu(II) in 4 M aqueous imidazole, and; ( ), the MXAN fit using the split-axial pyramidal model and including eight distant solvent waters at 4.2±0.3 Å. Insets: a. Expansion of: (○), the rising edge energy region, and; ( ), the fit the rising edge. b. ( ), the contribution to the XAS intensity made by the eight-water solvation shell, plotted on the same scale and shifted vertically by 1.1 normalized units.

Inline graphic — (○), the K-edge XAS of 0.10 M Cu(II) in 4 M aqueous imidazole, and; ( ), the MXAN fit using the split-axial pyramidal model and including eight distant solvent waters at 4.2±0.3 Å. Insets: a. Expansion of: (○), the rising edge energy region, and; ( ), the fit the rising edge. b. ( ), the contribution to the XAS intensity made by the eight-water solvation shell, plotted on the same scale and shifted vertically by 1.1 normalized units.