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. Author manuscript; available in PMC: 2013 Mar 7.
Published in final edited form as: J Am Chem Soc. 2012 Feb 22;134(9):4398–4407. doi: 10.1021/ja211768v

Table 1.

A table of the calculated probabilities spanning 100% ee to −100% ee for different mixtures of chiral imine stereogenic centers surrounding Fe(II).

%ee (R-R-R) (R-R-S) (S-S-R) (S-S-S) sum
100 1 0 0 0 1
80 0.73 0.25 −0.025 −0.00074 0.95
60 0.51 0.39 −0.094 −0.0071 0.80
40 0.34 0.45 −0.19 −0.025 0.58
20 0.21 0.44 −0.29 −0.061 0.30
0 0.12 0.38 −0.38 −0.12 0
−20 0.061 0.29 −0.44 −0.21 −0.30
−40 0.025 0.19 −0.45 −0.34 −0.58
−60 0.0071 0.094 −0.39 −0.51 −0.80
−80 0.00074 0.025 −0.25 −0.73 −0.95
−100 0 0 0 −1 −1