Table 1.

¹³C and ¹H NMR Data for Compounds 1, 2, and 8 in CDCl₃.^a

	1		2		8
no.	δC, mult.d	δH, mult. (J in Hz)b	δC, mult. d	δH, mult. (J in Hz)b	δC, mult. d	δH, mult. (J in Hz)c
1	75.5, CH	4.78, bs	76.3, CH	5.01, bs	173.4, C
2	22.7, CH2	1.85, m	23.5, CH2	1.92, dt (14.5, 3.1)	28.6, CH2	2.46, m
		1.76, m		1.76, dq (14.5, 3.5)		2.11, m
3	34.7, CH2	1.69, m	34.8, CH2	1.61, td (13.7, 3.4)	32.3, CH2	2.17
		1.32, dt (13.7, 3.2)		1.35, dt (13.7, 3.7)		1.97,
4	33.0, C		32.6, C		77.7, C
5	44.3, CH	1.74, dd (11.5, 6.0)	37.9, CH	2.51, dd (15.3, 5.8)	53.8	2.76
6	25.1, CH2	2.50, m	25.5, CH2	2.58, ddd (20.1, 5.7, 3.9)	27.7, CH2	1.82, m
		2.21, m		2.24, m		1.35, m
7	135.7, CH	6.88, bq (3.5)	139.9, CH	7.01, t (3.5)	27.9, CH2	1.22, bs
8	126.9, C		130.4, C		29.5, CH2	1.22, bs
9	42.9, CH	3.18, m	78.0, C		29.3, CH2	1.22, bs
10	37.5, C		41.0, C		29.5, CH2	1.22, bs
11	66.7, CH2	α 4.23, t (9.2)	73.9, CH2	4.40, d (10.1)	29.3, CH2	1.22, bs
		Β 4.02, t (9.2)		4.25, d (10.1)
12	169.7, C		168.5, C		31.9, CH2	1.22, bs
13	32.7, CH3	1.00, s	33.0, CH3	1.04, s	33.8, CH2	2.03, bq
						1.95, m
14	21.5, CH3	0.98, s	21.6, CH3	1.03, s	139.2, CH	5.78, ddt (17.1, 10.2, 6.8)
15	13.6, CH3	0.92, s	18.6, CH3	0.92, s	114.1, CH2	4.91, dt (10.2, 1.6)
						4.97, dq (17.1, 1.6)
16					174.4, C
17					174.4, C
1′	171.5, C		170.9, C		51.9, CH3	3.64, s
2′	57.4, CH	4.62, m	58.9, CH	4.36, dd (7.4, 5.8)	51.8, CH3	3.79, s
3′	31.1, CH	2.21, m	29.9, CH	2.20, m	53.1 CH3	3.70, s
4′	19.5, CH3	1.02, d (6.8)	19.4, CH3	1.02, d (7.0)
5′	17.3, CH3	0.93, d (7.0)	17.9, CH3	0.98, d (6.8)
Ac	170.2, C		169.9, C
Ac CH3	23.3, CH3	2.08, s	23.2, CH3	2.07, s
NH		5.90, bd (8.4)		5.94, bd (6.8)

^aAll assignments are based on COSY, HSQC, HMBC and NOE experiments.

^b300 MHz for ¹H NMR, HMBC, COSY.

^c500 MHz for ¹H NMR, HMBC, COSY.

^d75 MHz for ¹³C NMR