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. Author manuscript; available in PMC: 2012 Apr 23.
Published in final edited form as: J Phys Chem A. 2010 Nov 4;114(43):11483–11491. doi: 10.1021/jp103608d

Table 1.

Multi-exponential fit parameters to transient absorption data (810 nm pump, 750 nm probe).

parameters Sepia eumelanin black hair synthetic pheomelanin red hair
A1 0.68 +/− 0.10 0.73 +/− 0.05 0.60 +/− 0.04 0.49 +/− 0.04
τ1 (ps) 0.38 +/− 0.10 0.36 +/− 0.06 0.47 +/− 0.07 0.53 +/− 0.10
A2 0.24 +/− 0.10 0.20 +/− 0.04 0.35 +/− 0.05 0.38 +/− 0.04
τ2 (ps) 2.2 +/− 0.9 2.2 +/− 0.6 2.4 +/− 0.4 3.3 +/− 0.6
A3 0.06 +/− 0.02 0.04 +/− 0.01 0.048 +/− 0.01 0.11 +/− 0.02
τ3 (ps) 64 +/− 35 80 +/− 60 38+/− 13 41 +/− 20
A4 0.02 +/− 0.005 0.03 +/− 0.004 0.002 +/− 0.001 0.02 +/− 0.006
τ4 (ns)* 200 +/− 80 160 +/− 30 220 +/− 190 100 +/− 70
*

τ4 was determined by examining the phase shift of data before time zero analogous to frequency domain fluorescence lifetime measurements.