Table 2.
PPG standards identified using paper spray mass spectrometry. The PPG mass spectrum was obtained with excitation and detection frequency range of 1.5 MHz.
| PPG | Experimental m/z | Theoretical m/z | Mass measurement error (Δppm) | Mass resolving power (M/ΔM50%) | [C3O2H7(C3H6O)nC6H13O2+Na]+ |
|---|---|---|---|---|---|
| 1666.17197 | 1666.17200 | −0.02 | 22686 | n = 25 | |
| 1724.21224 | 1724.21386 | −0.94 | 23629 | n = 26 | |
| 1782.25781 | 1782.25573 | 1.17 | 23817 | n = 27 | |
| 1840.29829 | 1840.29760 | 0.37 | 23808 | n = 28 | |
| 1898.34113 | 1898.33946 | 0.88 | 23139 | n = 29 | |
| 1956.37992 | 1956.38133 | −0.72 | 22968 | n = 30 | |
| 2014.41937 | 2014.42319 | −1.90 | 22638 | n = 31 | |
| 2072.46849 | 2072.46505 | 1.66 | 21991 | n = 32 | |
| 2130.50088 | 2130.50692 | −2.84 | 21503 | n = 33 | |
| 2188.55370 | 2188.54878 | 2.25 | 20679 | n = 34 | |
| 2246.59219 | 2246.59065 | 0.69 | 19685 | n = 35 | |
| 2304.63182 | 2304.63254 | −0.31 | 17868 | n = 36 | |
| 2362.67370 | 2362.67438 | −0.29 | 16365 | n = 37 |