Table 1.
Product ions formed on CID analysis of NNAL and alkylated derivatives
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---|---|---|---|---|---|---|---|---|
R1 | R2 | [M]+ | a | b | c | d | e | f |
H | CH3 | 210 | 180 | 149 | 121 | 108 | 93 | 80 |
H | CD3 | 213 | 183 | 149 | 121 | 108 | 93 | 80 |
CH3 | CH3 | 224 | 194 | 163 | 135 | 122 | 107 | 94 |
CH3 | CD3 | 227 | 197 | 163 | 135 | 122 | 107 | 94 |
C2H5 | CH3 | 238 | 208 | 177 | 149 | 136 | 121 | 108 |
C2H5 | CD3 | 241 | 211 | 177 | 149 | 136 | 121 | 108 |
C3H7 | CH3 | 252 | 222 | 191 | 163 | 150 | 135 | 122 |
C3H7 | CD3 | 255 | 225 | 191 | 163 | 150 | 135 | 122 |