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. Author manuscript; available in PMC: 2012 Jun 3.
Published in final edited form as: J Org Chem. 2011 Apr 29;76(11):4697–4702. doi: 10.1021/jo200360s

TABLE 3. CuI Assisted Olefin Metathesis Reactionsa.

graphic file with name nihms293196u5.jpg

substrate olefinic partner product yield (%)b,c
graphic file with name nihms293196t1.jpg graphic file with name nihms293196t2.jpg graphic file with name nihms293196t3.jpg 82
>20:1
graphic file with name nihms293196t1.jpg graphic file with name nihms293196t4.jpg graphic file with name nihms293196t5.jpg 98
>20:1
graphic file with name nihms293196t1.jpg graphic file with name nihms293196t6.jpg graphic file with name nihms293196t7.jpg 93
>20:1
graphic file with name nihms293196t1.jpg graphic file with name nihms293196t8.jpg graphic file with name nihms293196t9.jpg 93
E only
graphic file with name nihms293196t10.jpg graphic file with name nihms293196t6.jpg graphic file with name nihms293196t11.jpg 84
>20:1
graphic file with name nihms293196t12.jpg graphic file with name nihms293196t8.jpg graphic file with name nihms293196t13.jpg 94
E only
a

Reactions were conducted at 0.5 mmol scale.

b

Isolated yields.

c

E/Z ratio was determined by 1H NMR.