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. Author manuscript; available in PMC: 2013 May 9.
Published in final edited form as: J Am Chem Soc. 2012 May 1;134(18):7963–7970. doi: 10.1021/ja302260d

Scheme 2. Synthesis of cis-series quasiisomers 13e-h.

Scheme 2

The minor allylation products could not be separated so the products 12 were silylated directly. Numbers in parentheses are epimer ratios of the tagged quasiisomers at C7.