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. Author manuscript; available in PMC: 2013 May 1.
Published in final edited form as: J Mater Sci Mater Med. 2012 Mar 20;23(5):1157–1172. doi: 10.1007/s10856-012-4595-5

Table 1.

a. Chemical structures and experimental parameters for the polymerized dentin adhesives in group 1 (the mean values ±the standard deviation of at least three replicates are shown).
Group 1 graphic file with name nihms366910t1.jpg graphic file with name nihms366910t2.jpg graphic file with name nihms366910t3.jpg graphic file with name nihms366910t4.jpg
Chemical Name Ethylene glycol dimethacrylate Diethylene glycol dimethacrylate Triethylene glycol dimethacrylate Tetraethylene glycol dimethacrylate
Abbreviation EGDMA DEGDMA TEGDMA T4EGDMA
Degree of Conversion (%) 88.0±0.0 92.5 ±0.8 92.7±0.6 92.5±0.8
Sorption (%) 7.4±0.17 8.59±0.09 9.03±0.3 12.2±0.98
Solubility (%) 1.8±0.34 0.9±0.21 0.6±0.17 3.53±0.95
Rubbery Modulus (× 10 MPa) 108±8.06 38.8±3.21 35.3±5.77 38.5±6.82
Glass transition temperature (°C) 130.7±7.7 152.8±0.7 141.1±1.1 131.2±2.6
Crosslink Density (molm−3) 10719.3±205.6 3660±319 3420±587 3820±753
Partition Coefficient 0.09±0.0022 0.107±0.0012 0.109±0.0091 0.146±0.0
Density (g/cm3) 1.238±0.01 1.242±0.01 1.204±0.05 1.232±0.01
Leachable Density (× 10−2 g/cm3) 2.23±0.44 1.12±0.27 0.72±0.23 4.36±1.21
Log P (mol avg.) 1.295 1.243 1.203 1.175
D of water (× 10−8 cm2/sec) 1.36 1.891 2.16 3.148
D of leachable (× 10−9 cm2/sec) 2.184 3.162 1.733 3.526
b. Chemical structures and experimental parameters for the polymerized dentin adhesives in group 2 (the mean values ±the standard deviation of at least three replicates are shown).
Group 2 graphic file with name nihms366910t5.jpg graphic file with name nihms366910t6.jpg graphic file with name nihms366910t7.jpg graphic file with name nihms366910t8.jpg graphic file with name nihms366910t9.jpg
Chemical Name 1,6-hexanediol dimethacrylate Neopentyl glycol dimethacrylate 1,4-butanediol dimethacrylate 1,3-butanediol dimethacrylate Ethylene glycol dimethacrylate
Abbreviation 1,6-HDMA NGDMA 1,4-BDMA 1,3-BDMA EGDMA
Degree of Conversion (%) 91.5±0.9 88.5±3.0 91.7±0.4 89.6±0.1 88.2±0.5
Sorption (%) 9.25±0.48 9.95±0.98 6.9±0.15 7.2±0.04 7.40±0.17
Solubility (%) 2.66±0.27 2.75±0.75 0.80±0.26 0.9±0.05 1.80±0.34
Rubbery Modulus (× 10 MPa) 56.9±9.9 54.9±7.93 81.8±5.69 154.0±2.57 108±8.06
Glass transition temperature (°C) 150.0±4.8 168.3±2.0 147.8±4.3 153.7±2.6 130.7±7.7
Crosslink Density (molm−3) 5400±111 4990±779 7790±771 18500±1840 10800±1440
Partition Coefficient 0.112±0.00 0.107±0.0045 0.084±0.0018 0.088±0.00 0.09±0.0022
Density (g/cm3) 1.208±0.01 1.208±0.02 1.221±0.01 1.222±0.00 1.238±0.01
Leachable Density (× 10−2 g/cm3) 3.21±0.35 3.32±0.97 0.98±0.33 1.10±0.06 2.23±0.44
Log P (mol avg.) 1.543 1.524 1.4 1.372 1.295
D of water (× 10−8 cm2/sec) 1.721 1.497 1.358 1.406 1.36
D of leachable (× 10−9 cm2/sec) 7.456 4.634 7.931 1.026 2.184
c. Chemical structures and experimental parameters for the polymerized dentin adhesives from formulations other than groups 1 and 2 (the mean values ± the standard deviation of at least three replicates are shown).
Other
monomers		 graphic file with name nihms366910t10.jpg graphic file with name nihms366910t11.jpg graphic file with name nihms366910t12.jpg graphic file with name nihms366910t13.jpg graphic file with name nihms366910t14.jpg graphic file with name nihms366910t15.jpg
Chemical
Name		 Pentaerythritol
imethacrylate		 Trimethylolpropane
trimethacrylate		 Pentaerythritol
trimethacrylate		 1,3-glycerol
dimethacrylate		 Glyceryl
trimethacrylate		 Bisphenol A
ethoxylate
dimethacrylate		 Diurethane
dimethacrylate		 Bisphenol A-
glycerolate
dimethacrylate
Abbreviation PEDMA TMTMA PETMA GDMA GTMA BisEMA UDMA BisGMA
Degree of Conversion (%) 88.4±0.9 85.9±1.9 84.0±1.5 89.6±0.4 84.2±1.6 93.4±0.4 92.8±0.3 88.0±0.0
Sorption (%) 9.25±0.09 6.93±0.26 10.2±0.44 9.89±0.53 6.74±0.09 7.51±0.2 7.61±0.2 7.5±0.12
Solubility (%) 2.88±0.45 2.00±0.05 4.82±0.96 1.10±0.27 1.00±0.14 1.10±0.26 0±0.16 0.3±0.02
Rubbery Modulus (× 10 MPa) 55.3±5.68 186±25.4 122±18.4 69.8±9.57 38.8±3.21 18.9±1.75 22.6±2.53 24.1±3.14
Glass transition temperature (°C) 154.7±8.2 156±2.6 155.2±4.1 166.0±1.2 164.2±3.3 111.1±1.9 130.6±0.8 142.0±1.8
Crosslink Density (molm−3) 5190±807 17400±266 11400±2050 6830±923 26400±190 1980±216 2250±264 2330±333
Partition Coefficient 0.102±0.0019 0.087±0.0013 0.113±0.0115 0.124±0.0015 0.085±0.0019 0.092±0.0028 0.092±0.0025 0.105±0.0037
Density (g/cm3) 1.204±0.01 1.236±0.01 1.227±0.06 1.257±0.01 1.259±0.01 1.224±0.2 1.215±0.01 1.206±0.02
Leachable Density (× 10−2 g/cm3) 3.47±0.57 2.47±0.07 5.91±1.44 1.38±0.34 1.26±0.19 1.35±0.33 0.00±0.00 0.36±0.02
Log P (mol avg.) 1.067 1.529 1.276 1.166 1.373 1.767 1.800 1.738
D of water (× 10−8 cm2/sec) 1.532 1.060 2.542 2.382 1.172 1.563 1.334 1.882
D of leachable (× 10−9 cm2/sec) 4.445 3.048 7.33 22.13 1.769 0.6412 2.003 0.7882