Table 3.
Molecular weights and binding constants determined as mol N-groups per dm3 for the studied PBAEs. These binding constants were converted to the binding constants per molecule by Ki′ = (average molecular weight of the polymer/molecular weight per N-group)×Ki. The values for PEIs are from reference [18].
PBAE |
Mav (kDa) |
Ktot (dm3 molN-1)b |
Ktot′ (dm3 molpolymer-1)c |
---|---|---|---|
F28 | 16.1 | 3870 | 2.1 × 105 |
C36 | 21.2 | 2090 | 1.4 × 105 |
D24 | 9.5 | 4020 | 7.5 × 104 |
E28 | 14.3 | 4550 | 2.1 × 105 |
U28 | 15.6 | 3950 | 1.5 × 105 |
C28 | 27.9 | 6220 | 6.0 × 105 |
AA24 | 8.1 | 2690 | 5.0 × 104 |
AA28 | 20.9 | 4700 | 2.3 × 105 |
C32 | 18.1 | 4440 | 2.7 × 105 |
JJ28 | 16.8 | 6100 | 3.4 × 105 |
linear PEI | 22.0 | 6600 | 3.4 × 106 |
branched PEI | 25.0 | 2100 | 1.2 × 106 |
branched PEI | 0.7 | 4700 | 7.6 × 104 |
dm3 per mol N-groups
dm3 per mol polymer molecules