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. Author manuscript; available in PMC: 2013 May 14.
Published in final edited form as: Biomacromolecules. 2012 Apr 3;13(5):1400–1409. doi: 10.1021/bm300135h

Table 3.

Estimated parameters for the energy landscape of the mucin self-interactions

Sample rf (nN/s) f* (pN) koff (s−1) xβ (nm) xβ
mean
(nm)
xβa
mean
(nm)
R2b
Tn 0.64 34 1.2 ± 0.27 0.52 ± 0.03 0.79
1.8 42 4.0 ± 0.67 0.37 ± 0.02 0.85
3.6 40 4.7 ± 0.79 0.45 ± 0.02 0.37 0.34 0.94
7.1 49 16.1 ± 2.0 0.28 ± 0.01 0.89
c 14 78 10.6 ± 2.6 0.23 ± 0.02 0.74
39 256 57 ± 13 0.02 ± 0.004 0.02 0.79

Tri 0.18 40 0.64 ± 0.8 0.30 ± 0.16 0.56
0.63 42 0.13 ± 0.1 0.65 ± 0.008 0.95
1.4 38 2.7 ± 1.0 0.43 ± 0.05 0.40 0.96
2.8 39 2.2 ± 0.8 0.55 ± 0.04 0.88
5.8 44 5.8 ± 1.0 0.45 ± 0.02 0.96
11 48 11 ± 2.0 0.39 ± 0.017 0.96

Asialo Tri 1.7 50 3.0 ± 1.5 0.30 ± 0.05 0.92
4.7 54 0.57 ± 0.2 0.54 ± 0.03 0.34 0.96
9.0 53 10 ± 1.5 0.32 ± 0.01 0.98
19 64 48 ± 16.1 0.19 ± 0.02 0.81

Asialo Fd 0.75 27 2.5 ± 1.1 0.56 ± 0.07 0.94
2.0 27 0.88 ± 0.4 0.93 ± 0.07 0.98
4.0 34 19 ± 2.9 0.36 ± 0.022 0.55 0.98
8.0 39 27 ± 8.5 0.32 ± 0.007 0.95
17 56 1.2 ± 1.7 0.56 ± 0.11 0.84
a

xβ from f* vs rf.

b

R2 = coefficient of determination

c

inner energy barrier has become the rate limiting.