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. Author manuscript; available in PMC: 2012 Jul 25.
Published in final edited form as: Angew Chem Int Ed Engl. 2011 Jun 17;50(31):7136–7139. doi: 10.1002/anie.201101364

Scheme 2.

Scheme 2

Hypothetical formation of higher-order enolates during the enolization of 1 with substoichiometric TiCl4. Bn =benzyl.