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. 2012 Mar 7;9(72):1705–1712. doi: 10.1098/rsif.2012.0003

Table 1.

Best-fit results obtained by EXAFS analysis of Pd foil, Au foil and bioPd–Al bimetallic sample.

sample Pd foil Au foil bioPd–Au
NPd−Pd 12a 1.9 (4)
NPd−Au 1.2b
NAu−Pd 0.8 (2)
NAu−Au 12a 9.9 (6)
NPd−M 3.1 (4)
NAu−M 10.7 (6)
cNM−M 7.8 (6)
RPd−Pd (Å) 2.74 (14) 2.76 (16)
RPd−Au (Å) 2.75 (17)
RAu−Au (Å) 2.84 (19) 2.84 (18)
σ2Pd−Pd2) 0.0058 (58) 0.0060 (6)
σ2Pd−Au2) 0.0077 (72) 0.0039 (4)
σ2Au−Au2) 0.0088 (9)

aValue fixed for calculation.

bCoordination numbers were constrained in the fits to be varied in accordance with equation: NPd−Au/NAu−Pd = XAu/XPd.

cNM−M = XAuNAu−M + XPdNPd−M (where XAu and XPd are the molar composition of Au and Pd, respectively).