Table 2.
no. | catalyst 2.5% Au/2.5%Pd on support as shown | reaction conditions |
(metal) (10−5 mol l−1 alcohol) |
TOF (h−1)a at 0.5 h | reference | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|
catalyst (g) | alcohol (l) | T (K) | P (105 Pa) | gas | S (r.p.m.) | Au | Pd | ||||
1 | E. coli | 0.180 | 0.05 | 363 | 6 | air | 1200 | 44.6 | 82.5 | 1083 | this study |
2 | E. coli | 0.090 | 0.025 | 363 | 1 | O2 | 1200 | 44.6 | 82.5 | 887 | [31] |
3 | TiO2 | 0.200 | 0.04 | 373 | 2 | O2 | 1500 | 63.5 | 118 | 607 | [14] |
4 | TiO2 | 0.007 | 0.04 | 373 | 1 | O2 | 1500 | 2.1 | 3.9 | 6190 | [14] |
5 | TiO2 | 0.007 | 0.04 | 373 | 5 | O2 | 1500 | 2.1 | 3.9 | 6190 | [14] |
6 | TiO2 | 0.007 | 0.04 | 383 | 1 | O2 | 1500 | 2.1 | 3.9 | 14 270 | [14] |
7 | TiO2 | 0.007 | 0.04 | 433 | 1 | O2 | 1500 | 2.1 | 3.9 | 86 500 | [14] |
8 | TiO2 | 0.007 | 0.04 | 433 | 10 | O2 | 1500 | 2.1 | 3.9 | 65 400 | [32] |
9 | TiO2 | 0.025 | 0.04 | 393 | 10 | O2 | 1500 | 7.9 | 14.7 | 1300 | [33] |
10 | TiO2 | 0.025 | 0.04 | 433 | 10 | O2 | 1500 | 7.9 | 14.7 | 28 400 | [33] |
aCalculation of turnover frequency (TOF, h−1) after 0.5 h of reaction. TOF is defined as molecules reacting per active site in unit time. Here, TOF numbers were calculated on the basis of the total loading of metals. P, pressure; S, stirrer speed.