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. 2012 Mar 7;9(72):1705–1712. doi: 10.1098/rsif.2012.0003

Table 2.

Comparison of the catalytic activity of the biocatalyst for benzyl alcohol oxidation with data from the literature.

no. catalyst 2.5% Au/2.5%Pd on support as shown reaction conditions
(metal) (10−5 mol l−1 alcohol)
TOF (h−1)a at 0.5 h reference
catalyst (g) alcohol (l) T (K) P (105 Pa) gas S (r.p.m.) Au Pd
1 E. coli 0.180 0.05 363 6 air 1200 44.6 82.5 1083 this study
2 E. coli 0.090 0.025 363 1 O2 1200 44.6 82.5 887 [31]
3 TiO2 0.200 0.04 373 2 O2 1500 63.5 118 607 [14]
4 TiO2 0.007 0.04 373 1 O2 1500 2.1 3.9 6190 [14]
5 TiO2 0.007 0.04 373 5 O2 1500 2.1 3.9 6190 [14]
6 TiO2 0.007 0.04 383 1 O2 1500 2.1 3.9 14 270 [14]
7 TiO2 0.007 0.04 433 1 O2 1500 2.1 3.9 86 500 [14]
8 TiO2 0.007 0.04 433 10 O2 1500 2.1 3.9 65 400 [32]
9 TiO2 0.025 0.04 393 10 O2 1500 7.9 14.7 1300 [33]
10 TiO2 0.025 0.04 433 10 O2 1500 7.9 14.7 28 400 [33]

aCalculation of turnover frequency (TOF, h−1) after 0.5 h of reaction. TOF is defined as molecules reacting per active site in unit time. Here, TOF numbers were calculated on the basis of the total loading of metals. P, pressure; S, stirrer speed.