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. 2010 Dec 30;2(3):151–159. doi: 10.1021/cn100090g

Figure 3.

Figure 3

Preferred geometries (Spartan ’06) of cysteine thioester derivatives (3−9). Arrows point toward C10 of the fatty acid side chain. The hydrocarbon chain remains roughly linear for compounds 3−5 with a hairpin loop of the hydrocarbon chain at C10 for compounds 6−9. Thioester carbonyls are depicted by an asterisk (∗).