Table 3.

Luminescent Spectral Data and Lifetime Measurement for the Compounds in Solid State and Solution.

Compound	λmax, Solid (298 K)		λmax, Solid (77 K)		λmax, Solution (298 K) (DMSO)[a]		λmax, Solution (77 K) (DMSO)[b]
	λexc	λem [τ (μs)]	λexc	λem [τ(μs)]	λexc	λem [τ(μs)]	λexc	λem [τ (μs)]
5a [Au2Cl2(μ-dppe)]	325[c]	480[c]			--	---
1a [Au2(mes)2(μ-dppe)]	271 362	386 sh, 405[13], 430 [11], 449 sh	278–300 358	386 [37],409[43], 430 [57], 449 sh	--	---
2a [Au2Ag(μ-mes)2(μ-dppe)]ClO4	401	522 [18]	381	527 [17]	--	---	370	497 [15]
3a [Au2Ag(μ-mes)2(μ-dppe)]SO3CF3	408	523 [15]	386	527 [16]	--	---	362	480 [18], 500 sh
4a [Au2Cu(μ-mes)2(μ-dppe)]PF6	414	533 [12]	405	546 [13]	--	---	370	505 [16]
5b [Au2Cl2(μ-dppy)]	314	470 [7]	327	447 [11]	--	---	328	443 [11]
1b [Au2(mes)2(μ-dppy)]	415	505 [14]	375	438 [44], 494 [13]	--	---	347	426 [10]
2b [Au2Ag(μ-mes)2(μ-dppy)]ClO4	315 398	359 [10], 520[16] 520	390	522 [12]	339	524 [9]	385	511 [19]
3b [Au2Ag(μ-mes)2(μ-dppy)]SO3CF3	394	518 [14]	388	518 [14]	--	---	380	512 [16]
4b [Au2Cu(μ-mes)2(μ-dppy)]PF6	440	563 [9]	370	522 sh, 595 [10]	--	---	367	482 [11]

Data of wavelength are given in nm.

^[a]Data using DMSO as solvent at room temperature, 5 × 10⁻⁴ M.

^[b]Data in frozen solutions of DMSO, 5 × 10⁻⁴ M.

^[c]Data taken from reference [8g].