Table 8.

Thermodynamic Parameters (eV) for the One-electron Reduction Reaction 1, and One-electron Reduction Potentials (V) for TTCorrH₃, 2-NO₂TTCorrH₃, 3-NO₂TTCorrH₃, and 3,17-(NO₂)₂TTCorrH_3.

	$\Delta H_{\mathit{\text{ox}}/\mathit{\text{red}}}^o$	$-T\Delta S_{\mathit{\text{ox}}/\mathit{\text{red}}}^o$	ΔEsolva	$\Delta G_{\mathit{\text{ox}}/\mathit{\text{red}}}^o$	$E_{\mathit{\text{ox}}/\mathit{\text{red}}}^o$ vs SCE	E1/2bvs SCE
TTCorrH3	–2.93	0.02	–1.41	–2.91	–1.46	–1.40
2-(NO2)TTCorrH3	–3.49	0.03	–1.50	–3.52	–0.85	–
3-(NO2)TTCorrH3	–3.44	0.03	–1.47	–3.47	–0.90	–0.84
3,17-(NO2)2TTCorrH3	–3.78	0.04	–1.31	–3.82	–0.55	–0.62

^a $\Delta E_{\mathit{\text{solv}}}$ is the difference between the dielectric energy of the reduced species and the dielectric energy of the oxidized species.

^bExperimental values in dichloromethane solution, this work.