Table 1.
Selected bond distances and angles for 1.a
| Distance (Å) | |
|---|---|
| Mn1—O1 | 1.822(4) |
| Mn1—N1 | 2.043(5) |
| Mn1—N2 | 2.169(4) |
| Mn1—N3 | 2.022(4) |
| Mn1—N4 | 2.010(5) |
| N5—C7 | 1.338(7) |
| C7—O2 | 1.248(7) |
| O1⋯N5 | 2.654(5) |
| O1⋯N6 | 2.775(5) |
| O1⋯N7 | 2.773(5) |
| Angle (deg) | |
| N1—Mn1—O1 | 175.34(17) |
| N1—Mn1—N2 | 79.63(18) |
| N1—Mn1—N3 | 82.13(19) |
| N1—Mn1—N4 | 82.94(18) |
| N2—Mn1—N3 | 117.36(17) |
| N2—Mn1—N4 | 114.09(18) |
| N3—Mn1—N4 | 122.23(19) |
| O1—Mn1—N2 | 95.80(17) |
| O1—Mn1—N3 | 99.56(18) |
| O1—Mn1—N4 | 99.66(18) |
a
Average values are reported for the four anions in the asymmetric unit cell.