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. Author manuscript; available in PMC: 2012 Sep 5.
Published in final edited form as: Chembiochem. 2011 Jul 12;12(13):1984–1987. doi: 10.1002/cbic.201100336

Figure 2.

Figure 2

Relative configuration of C7 hydrogen substituents with π orbital of the sp3 hybridized C8 in SmCPSKSL1 catalyzed class II bicyclization. Depicted is putative moncyclic intermediate (R = allylic isoprenyl diphosphate “tail”), with Newman projection along the C7-C8 bond.