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. Author manuscript; available in PMC: 2012 Jun 27.
Published in final edited form as: Tetrahedron. 2011 Jun 17;67(24):4333–4343. doi: 10.1016/j.tet.2011.04.021

Table 1. Suzuki-Miyaura cross-coupling of (Z)-Br-1.

graphic file with name nihms288467u22.jpg
Entry 14 15 Conditions % Isolated yield
1 graphic file with name nihms288467t1.jpg graphic file with name nihms288467t2.jpg Pd2(dba)3, XPhos K3PO4, THF, 35 °C 55%
2 graphic file with name nihms288467t3.jpg graphic file with name nihms288467t4.jpg Pd2(dba)3, XPhos K3PO4, THF, 35 °C 85%
3 graphic file with name nihms288467t5.jpg graphic file with name nihms288467t6.jpg Pd2(dba)3, XPhos K3PO4, THF, 35 °C 64%
4 graphic file with name nihms288467t7.jpg graphic file with name nihms288467t8.jpg Pd2(dba)3, P(o-tol)3 Ag2O, THF, 23 °C 72%
5 graphic file with name nihms288467t9.jpg graphic file with name nihms288467t10.jpg Pd2(dba)3, P(o-tol)3 Ag2O, THF, 23 °C 92%
6 graphic file with name nihms288467t11.jpg graphic file with name nihms288467t12.jpg Pd(OAc)2, SPhos K3PO4, THF, 23 °C 70%
7 graphic file with name nihms288467t13.jpg graphic file with name nihms288467t14.jpg Pd(OAc)2, XPhos Cs2CO3, THF, 23 °C 64%
8 graphic file with name nihms288467t15.jpg graphic file with name nihms288467t16.jpg Pd(OAc)2, XPhos Cs2CO3, THF, 23 °C 60%