Table 1.
entry | substrate | product | yield(%)b |
---|---|---|---|
1 | |||
a) R = Me | 76 | ||
b) R = p-CIPh | 72 | ||
c) R = tBu | 76 | ||
d) R = Ph | 76 | ||
2 | 56 | ||
3 | |||
a) R = cyclopropyl | 62 | ||
b) R = Ph | 69 | ||
c) R = H | 70 | ||
4 | 76 |
Standard conditions: 10 mol % of PtCl2, 0.2 M in PhMe at 100 °C over 3 h.
Isolated yields after column chromatography are reported.