Table 1.
solvent | 2a | 2d | 7a | 2f | 7b | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| |||||||||||||||
abs | em | I/Imax | abs | em | I/Imax | abs | em | I/Imax | abs | em | I/Imax | abs | em | I/Imax | |
C6H12 | 343 | 392 | 0.01 | 347 | 407 | 0.01 | 362 | 433 | 0.77 | 397 | 449 | 0.72 | 418 | 507 | 1.00 |
PhMe | 349 | 416 | 0.32 | 353 | 417 | 0.15 | 368 | 452 | 0.74 | 403 | 478 | 1.00 | 426 | 554 | 0.58 |
PhCl | 354 | 425 | 0.63 | 357 | 423 | 0.32 | 370 | 462 | 0.89 | 402 | 498 | 0.96 | 427 | 573 | 0.39 |
EtOAc | 352 | 430 | 0.71 | 353 | 429 | 0.33 | 366 | 467 | 0.69 | 396 | 506 | 0.59 | 417 | 586 | 0.21 |
CH2Cl2 | 358 | 440 | 0.75 | 358 | 440 | 0.65 | 373 | 472 | 0.93 | 398 | 511 | 0.84 | 426 | 595 | 0.30 |
EtCOMe | 367 | 443 | 0.83 | 356 | 443 | 0.55 | 368 | 481 | 0.52 | 398 | 517 | 0.30 | 420 | 612 | 0.06 |
CH3CN | 368 | 456 | 0.85 | 356 | 448 | 0.79 | 370 | 489 | 0.90 | 396 | 523 | 0.24 | 419 | 625 | 0.03 |
DMSO | 369 | 464 | 0.87 | 363 | 453 | 0.84 | 376 | 472 | 1.00 | 407 | 538 | 0.25 | 428 | 643 | 0.03 |
iPrOH | 367 | 480 | 0.99 | 368 | 482 | 1.00 | 376 | 512 | 0.96 | 406 | 520 | 0.12 | 417 | 637 | <0.01 |
EtOH | 369 | 494 | 1.00 | 369 | 489 | 0.82 | 374 | 522 | 0.94 | 406 | 495 | 0.05 | 410 | 539 | 0.02 |
Maximum absorbance (abs) and fluorescence (em) in nm. I/Imax is the normalized, absorption-adjusted emission intensity over the range of solvents.