Table 3.
Some unmodified peptides yielding the unusual fragment ion a
| Sequence | ‘x’ m/z exp.b |
‘x’ m/z calc. |
Δ ppm |
|---|---|---|---|
| VLALPEPSPAAPTLR | 822.4538 | 822.4464 | 9 |
| DTHDQLSEPSEVR | 500.2472 | 500.2463 | 2 |
| <QLMHNGHPSEK | 373.1753 | 373.1717 | 9 |
| TPDSLEPSPLK | 454.2625 | 454.2659 | 7 |
| <QTPSGTASR | 588.2673 | 588.2736 | 11 |
Data were acquired on a QSTAR Pulsar mass spectrometer.
after internal calibration