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. Author manuscript; available in PMC: 2013 Jun 27.
Published in final edited form as: J Am Chem Soc. 2012 Jun 6;134(25):10693–10697. doi: 10.1021/ja304068t

Table 3.

Nickel-Catalyzed Borylation of Unactivated Tertiary Alkyl Halides

graphic file with name nihms383249t18.jpg
entry substrate yield (%) a
1 graphic file with name nihms383249t19.jpg 74
2 graphic file with name nihms383249t20.jpg 40
3 graphic file with name nihms383249t21.jpg 67
4 graphic file with name nihms383249t22.jpg 70b
5 graphic file with name nihms383249t23.jpg 72
6 graphic file with name nihms383249t24.jpg 70
7 graphic file with name nihms383249t25.jpg 52
8 graphic file with name nihms383249t26.jpg 62
9 graphic file with name nihms383249t27.jpg 66
a

Yield of purified product (average of two experiments).

b

Diastereoselectivity: 11:1 cis:trans.