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. Author manuscript; available in PMC: 2012 Aug 1.
Published in final edited form as: Angew Chem Int Ed Engl. 2011 Jun 20;50(32):7312–7314. doi: 10.1002/anie.201102543

Table 1.

Examination of different SCF3 sources.[a]

graphic file with name nihms368817u1.jpg
Entry SCF3 Source Additive Yield [%]
1 CsSCF3 none 10
2 AgSCF3 none 0
3 (Me)4NSCF3 None 20
4 AgSCF3 (Me)4NI 0
5 AgSCF3 (Bu)4NCl 0
6 AgSCF3 (Bu)4NBr 56
7 AgSCF3 (Bu)4NI 55
8 AgSCF3 Ph(Me)3NI 80
9 AgSCF3 Ph(Et)3NI >99
[a]

(COD)Pd(CH2TMS)2 (2.5 mol %), PhMe (4 mL); all reactions are run on 0.2 mmol scale and all reported yields are based on GC data