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. Author manuscript; available in PMC: 2012 Aug 1.
Published in final edited form as: Angew Chem Int Ed Engl. 2011 Jun 20;50(32):7312–7314. doi: 10.1002/anie.201102543

Table 2.

Examination of various ligands commonly employed in Pd-catalyzed reactions.[a]

graphic file with name nihms368817u2.jpg
Entry Ligand Time (h) Yield (%)
1 1 1 >99[b]
2 2 1.5 60[b]
3 3 1 84[b]
4 7 2 36[c]
5 8 2 3[c]
6 5 2 29[d]
7 6 2 0[d]
8 9 2 0[d]
9 4 2 <1[c]
[a]

PhMe (4 mL); all reactions are run on 0.2 mmol scale and all reported yields are based on GC data.

[b]

1.15 mol % Pd, 1.27 mol % L.

[c]

1.5 mol % Pd, 1.65 mol % L.

[d]

2.5 mol % Pd, 2.75 mol % L