Table 1.
Position | 1 | 2 | ||
---|---|---|---|---|
δH (J in Hz) a | δC (mult.) b | δH (J in Hz) a | δC (mult.) b | |
1 | 1.46 m; 0.98 m | 40.2 (CH2) c | 1.65 m | 39.9 (CH2) |
2 | 1.65 m; 1.40 m | 18.4 (CH2) | 1.54 m; 1.38 m | 18.2 (CH2) |
3 | 1.38 m; 1.19 m | 42.5 (CH2) | 1.36 m; 1.12 m | 42.0 (CH2) |
4 | 33.1 (C) | 33.3 (C) | ||
5 | 0.92 m | 57.6 (CH) | 0.80 m | 56.5 (CH) |
6 | 1.57 m; 1.38 m | 18.8 (CH2) | 1.61 m; 1.42 m | 18.6 (CH2) |
7 | 1.68 m; 1.10 m | 40.1 (CH2) | 1.74 m; 0.90 m | 41.7 (CH2) |
8 | 44.8 (C) | 37.3 (C) | ||
9 | 1.45 m | 61.0 (CH) | 0.88 m | 58.9 (CH) |
10 | 36.8 (C) | 37.5 (C) | ||
11 | 1.99 d (6.0); 1.43 m | 35.0 (CH2) | 1.70 m; 1.45 m | 27.5 (CH2) |
12 | 43.0 (C) | 3.40 br d (10.5) | 80.5 (CH) | |
13 | 2.20 dd (13.0, 2.5) | 47.5 (CH) | 42.0 (C) | |
14 | 2.64 dd (13.5, 13.0) | 39.6 (CH2) | 0.80 m | 58.1(CH) |
2.54 dd (13.5, 2.5) | ||||
15 | 196.8 (C) | 1.78 m; 1.36 m | 20.0 (CH2) | |
16 | 122.9 (C) | 2.20 m; 1.22 m | 25.6 (CH2) | |
17 | 159.0 (C) | 2.22 m | 39.2 (CH) | |
18 | 4.58 s | 75.9 (CH) | 1.86 m | 55.3 (CH) |
19 | 0.85 s | 33.5 (CH3) | 0.84 s | 33.2 (CH3) |
20 | 0.84 s | 21.3 (CH3) | 0.80 s | 21.3 (CH3) |
21 | 0.85 s | 16.2 (CH3) | 0.84 s | 17.3 (CH3) |
22 | 0.87 s | 15.6 (CH3) | 0.84 s | 16.3 (CH3) |
23 | 1.14 s | 23.4 (CH3) | 0.91 s | 9.8 (CH3) |
24 | 7.33 d (1.5) | 142.3 (CH) | 177.8 (C) | |
25 | 6.76 d (1.5) | 110.9 (CH) | 4.38 dd (9.5, 7.0) | 70.0 (CH2) |
4.09 dd (11.0, 10.0) |
a 500 MHz in CDCl3; b 125 MHz in CDCl3; c Numbers of attached protons were deduced by DEPT experiments.