Table 4.
Presence of hypothetical products of reaction between tin octoate and α-methylstyrene detected at different catalyst : α-methylstyrene ratios.
| N | Hypothetical products of reaction | Molecular mass, a.m.u. | Molar ratio catalyst : methylstyrene | ||
|---|---|---|---|---|---|
| 1 : 2,5 | 1 : 125 | 1 : 300 | |||
| 1 | R–CO–O–Sn–O–CO–R | 405.12 | + | + | |
| 2 | Ms–CO–O–Sn–O–CO–R | 422.94 | + | ||
| 3 | Ms–O–Sn–O–CO–R | 394.94 | + | + | |
| 4 | Ms–Sn–O–CO–R | 378.95 | + | + | + |
| 5 | Ms–CO–O–Sn–O–CO–Ms | 441.34 | + | ||
| 6 | Ms–CO–O–Sn–O–Ms | 413.33 | + | + | + |
| 7 | Ms–CO–O–Sn–Ms | 397.34 | + | + | + |
| 8 | Ms–O–Sn–O–Ms | 385.05 | + | + | + |
| 9 | Ms–O–Sn–Ms | 369.06 | + | ||
| 10 | 3Ms–Sn | 470.25 | + | + | |
| 11 | 4Ms–Sn | 587.43 | + | ||
| 12 | R–Ms–R | 314.32 | + | ||
| 13 | R–CO–O–Ms | 260.24 | + | + | |
| 14 | R–CO–Ms | 244.25 | + | ||
–O–CO–R is an anion of octanoic acid and R = CH(CH2CH3)–(CH2)3–CH3 (99.07 a.m.u.); + denotes the presence of the stated mass in MALDI-TOF spectrum; Ms : α-methylstyrene.