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. 2012 Jul 5;2012:390947. doi: 10.1155/2012/390947

Table 4.

Presence of hypothetical products of reaction between tin octoate and α-methylstyrene detected at different catalyst : α-methylstyrene ratios.

N Hypothetical products of reaction Molecular mass, a.m.u. Molar ratio catalyst : methylstyrene
1 : 2,5 1 : 125 1 : 300
1 R–CO–O–Sn–O–CO–R 405.12 + +
2 Ms–CO–O–Sn–O–CO–R 422.94 +
3 Ms–O–Sn–O–CO–R 394.94 + +
4 Ms–Sn–O–CO–R 378.95 + + +
5 Ms–CO–O–Sn–O–CO–Ms 441.34 +
6 Ms–CO–O–Sn–O–Ms 413.33 + + +
7 Ms–CO–O–Sn–Ms 397.34 + + +
8 Ms–O–Sn–O–Ms 385.05 + + +
9 Ms–O–Sn–Ms 369.06 +
10 3Ms–Sn 470.25 + +
11 4Ms–Sn 587.43 +
12 R–Ms–R 314.32 +
13 R–CO–O–Ms 260.24 + +
14 R–CO–Ms 244.25 +

–O–CO–R is an anion of octanoic acid and R = CH(CH2CH3)–(CH2)3–CH3 (99.07 a.m.u.); + denotes the presence of the stated mass in MALDI-TOF spectrum; Ms : α-methylstyrene.