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. Author manuscript; available in PMC: 2012 Aug 1.
Published in final edited form as: Angew Chem Int Ed Engl. 2010 Jul 26;49(32):5541–5544. doi: 10.1002/anie.201000957

Table 2.

Single coupling of 1 with ArBr[a] (Scheme 1)

Entry Ar = yield[b]
2a graphic file with name nihms376647t1.jpg 91
2b graphic file with name nihms376647t2.jpg 92
2c graphic file with name nihms376647t3.jpg 90
2d graphic file with name nihms376647t4.jpg 83
2e graphic file with name nihms376647t5.jpg 88
2f graphic file with name nihms376647t6.jpg 91
2g graphic file with name nihms376647t7.jpg 94
2h graphic file with name nihms376647t8.jpg 91
2j graphic file with name nihms376647t9.jpg 81
2k graphic file with name nihms376647t10.jpg 89
[a]

Conducted at 55–60 °C using 1.5 equiv. LiN(SiMe3)2, 1.5 equiv. ArBr, 3–5 mol % PdCl2(PPh3)2, and THF as solvent

[b]

Isolated yields.