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Progress of reactions of (A) pyriplatin and phenanthriplatin with 16 equiv of 5′-dGMP at 37 °C or (B) 1 equiv of N-acetyl methionine (N-AcMet) at 37 °C, both in 10 mM PBS buffer (pH* = 7.4) monitored by 1H NMR spectroscopy. pH* refers to a pH measurement uncorrected for the effect of deuterium on the electrode.
