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. Author manuscript; available in PMC: 2012 Aug 7.
Published in final edited form as: J Phys Chem B. 2009 Sep 3;113(35):12084–12089. doi: 10.1021/jp903078x

Table I.

Apparent and Corrected Radiative Lifetimes for Dipeptides at 350 nm, pH 5.2

Dipeptides
And
Standard
Qrel <τ> δ IB
I
IB
II
“τrad”=
<τ>/Qrel
τ’rad =
τrad
τcorr =
τ’rad*IB
I II
NATA 1.0 2.96 ns 1.0 1.0 1.0 2.96 2.96 2.96 2.96
L-Trp 0.73 2.71 ns 1.0 0.82 0.80 3.71 3.71 3.04 2.97
Trp-Ala 0.381 1.33 ns 1.15 0.82 0.80 4.01 3.49 2.86 2.80
Trp-Phe 0.331 1.60 ns 1.06 0.90 0.74 4.83 4.56 4.10 3.36
Trp-Gly 0.335 1.38 ns 1.0 0.76 0.74 4.12 4.12 3.13 3.10
Trp-Leu 0.404 2.24 ns 1.22 0.67 0.67 5.54 4.50 3.02 3.02
Leu-Trp 0.215 1.18 ns 1.0 0.54 0.54 5.49 5.49 2.96 2.96
Val-Trp 0.237 1.18 ns 1.14 0.90 0.75 4.98 4.36 3.92 3.27
Gly-Trp 0.144 0.81 ns 1.28 0.77 0.77 5.63 4.39 3.38 3.38