Table 4.
Time-Resolved Decay Analysisa
A1 | τ 1 | A2 | τ 2 | A3 | τ 3 | Adark | Krad = (1/τrad) | τ mol | τrad = (τmol/Q) | ||
---|---|---|---|---|---|---|---|---|---|---|---|
SS A·6MI | 0.010 | 1.00 | 0.005 | 4.7 | 0.039 | 0.21 | 0.056 | 0.054 | 0.809 | 0.044 | 18.4 |
DS A·6MI | 0.009 | 0.93 | 0.003 | 5.59 | 0.041 | 0.34 | 0.057 | 0.053 | 0.703 | 0.037 | 19.0 |
SS T·6MI | 0.014 | 1.52 | 0.020 | 4.2 | 0.009 | 0.21 | 0.067 | 0.043 | 2.478 | 0.107 | 23.2 |
DS T·6MI | 0.041 | 2.37 | 0.021 | 4.12 | 0.005 | 0.39 | 0.042 | 0.068 | 2.772 | 0.189 | 14.7 |
SS A·3MI | 0.002 | 1.03 | 0.003 | 4.28 | 0.005 | 0.15 | 0.125 | 0.010 | 1.491 | 0.015 | 99.4 |
DS A·3MI | 0.003 | 1.25 | 0.004 | 5.72 | 0.019 | 0.14 | 0.110 | 0.025 | 1.041 | 0.026 | 40.0 |
SS T·3MI | 0.023 | 1.77 | 0.008 | 4.55 | 0.014 | 0.52 | 0.090 | 0.045 | 1.869 | 0.084 | 22.2 |
DS T·3MI | 0.009 | 1.67 | 0.003 | 4.91 | 0.006 | 0.37 | 0.118 | 0.017 | 1.837 | 0.032 | 57.4 |
6MI | 96.8% | 6.3 | 3.2% | 2.8 | (0) | 0.110 | 6.2 | 0.70 | 8.9 | ||
3MI | 100% | 6.5 | (0) | 0.135 | 6.5 | 0.88 | 7.4 |
See Materials and Methods for the definition of terms. An (n = 1–3) values are absolute alphas. τn values are the lifetimes of corresponding components. Krad is the radiative rate. τrad is the radiative lifetime. τmol is the molecular lifetime. is the quantum yield.