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. Author manuscript; available in PMC: 2013 Jul 18.
Published in final edited form as: Ind Eng Chem Res. 2012 Jun 19;51(28):9581–9590. doi: 10.1021/ie301031u

Table 2.

Reactions for the “green” synthesis of Fe/Pd bimetallic nanoparticles by ascorbic acid. (see Figure 1 for chemical structures)

Reaction E0 value (V)
2 Ascorbic acid → 2 dehydroascorbic acid + 4 e- + 4H+ -0.116
2/3 Fe3+ + 2e- → 2/3 Fe0 -0.0247
Pd2+ + 2e- → Pd0 +0.951
Overall:
2 Ascorbic acid + 2/3 Fe3+ + Pd2+ → 2 dehydroascorbic acid + 2/3 Fe0 + Pd0 + 4H+ +0.810V