The long-term global cycles of carbon and sulfur
(pyrite, FeS2). Because little carbon can be stored in the
ocean, inequalities between the weathering and burial of organic matter
must result in the reciprocal formation or loss of CaCO3 to
conserve carbon. The same is true for pyrite (FeS2),
calcium sulfate, and sulfur. Also, any prolonged imbalance in the net
flux between oxidized and reduced reservoirs of carbon must be balanced
approximately by opposite fluxes between reduced and oxidized
reservoirs of sulfur to avoid fluctuations in atmospheric
O2 that would be too large for the maintenance of higher
forms of life over geologic time. (Degassing caused by the deep thermal
decomposition of organic matter and pyrite is here lumped under the
heading of “weathering,” because the overall process of
degassing, followed by air oxidation, results in an overall reaction
chemically equivalent to oxidative weathering on the continents.)