Table II.
Compound | Mol wt. (g/mol) | T m (°C) | T g (°C) | T r a | ΔC p (J/g·K) | Rotatable bonds | ΔH f (kJ/mol) | ΔS f (J/mol·K) |
---|---|---|---|---|---|---|---|---|
Carbamazepine | 236 | 190 | 55 | 0.18 | 0.38 | 0 | 24.7 | 53.5 |
Piroxicam | 331 | 201 | 61 | 0.22 | 0.46 | 2 | 34.8 | 73.5 |
Griseofulvin | 352 | 218 | 88 | 0.24 | 0.46 | 3 | 39.6 | 80.8 |
Ursodiol | 392 | 203 | 103 | 0.49 | 0.48 | 4 | 37.6 | 78.9 |
Indomethacin | 357 | 160 | 45 | 0.58 | 0.47 | 5 | 38.4 | 88.9 |
Ketoconazole | 531 | 148 | 45 | 0.68 | 0.47 | 7 | 52.2 | 123.9 |
aReduced crystallization temperature T r = (T c − T g)/(T m − T g)