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. Author manuscript; available in PMC: 2013 Aug 22.
Published in final edited form as: Tetrahedron Lett. 2012 Jun 7;53(34):4494–4497. doi: 10.1016/j.tetlet.2012.05.138

Table 2.

Interceptive decarboxylative allylation of allyl nitroalkanoates with Meldrum’s acid derived Michael acceptors.

graphic file with name nihms392210t2.jpg
Entry R Solvent Temp
(°C)		 Time
(h)		 % Yield
(dr)a
1 H DCM rt 12 trace
2 H DCM 40 12 trace
3 H DCE 80 12 trace
4 H THF rt 12 74 (7:3)
5 H Tol rt 12 70 (7:3)
6 n-Pr THF 60 1 55 (7:3)
a

The relative configuration of the major diastereomer is not known.