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. Author manuscript; available in PMC: 2012 Sep 2.

Published in final edited form as: J Am Chem Soc. 2010 Aug 11;132(31):10920–10934. doi: 10.1021/ja102670n

Table 5. Thermal properties for RSC PLGAs.

	Precipitate		Annealed^a

Polymer	T_g (°C)	T_m (°C)	T_g (°C)	T_m (°C)
LG	57^b	ND	49^c	ND
L_racG	55^b	ND	48^c	ND
GLGL_R	50^b	ND	---	---
GLG	50^b	ND	43^c	ND
GL_racG	50^b	ND	---	---
LLG	57^b	ND	50^c	114^c
L_RLG	50^b	154^c	---	---
LL_RG	48^b	158^c	48^c	155^c
LLGLL G	52^b	ND	48^c	ND
L_RLGLLG	52^b	ND	48^c	ND
LLG	51^b	ND	47^c	ND
L_racLG	51^b	ND	48^c	ND
LL_racG	53^b	ND	48^c	ND

^a

Polymer films were drop-cast into DSC pans, dried under vacuum and annealed at 85°C for 3 h;

^b

Transitions were measured in second heating cycle;

^c

Transitions were measured in the first cycle.