Poly[[μ-(3-amino­pyridine)-κ2 N:N′-μ-chlorido-chlorido(N,N′-dimethyl­formamide-κO)nickel(II)] N,N′-dimethyl­formamide monosolvate]

. 2012 Aug 25;68(Pt 9):m1204–m1205. doi: 10.1107/S1600536812036215

Ni—O1	2.0607 (13)	C7—H7B	0.9600
Ni—N1	2.0860 (16)	C7—H7C	0.9600
Ni—N2ⁱ	2.1593 (17)	C8—N3	1.462 (3)
Ni—Cl1	2.4124 (5)	C8—H8A	0.9600
Ni—Cl2	2.4139 (5)	C8—H8B	0.9600
Ni—Cl1ⁱⁱ	2.4833 (5)	C8—H8C	0.9600
C1—N1	1.343 (2)	C9—O2	1.216 (2)
C1—C2	1.380 (3)	C9—N4	1.305 (3)
C1—H1A	0.9300	C9—H9A	0.9300
C2—C3	1.380 (3)	C10—N4	1.449 (3)
C2—H2A	0.9300	C10—H10A	0.9600
C3—C4	1.388 (3)	C10—H10B	0.9600
C3—H3A	0.9300	C10—H10C	0.9600
C4—C5	1.388 (3)	C11—N4	1.454 (3)
C4—N2	1.417 (2)	C11—H11A	0.9600
C5—N1	1.343 (2)	C11—H11B	0.9600
C5—H5A	0.9300	C11—H11C	0.9600
C6—O1	1.236 (2)	N2—Niⁱⁱⁱ	2.1593 (17)
C6—N3	1.322 (3)	N2—H2NA	0.89 (2)
C6—H6A	0.9300	N2—H2NB	0.82 (2)
C7—N3	1.462 (3)	Cl1—Niⁱⁱ	2.4833 (5)
C7—H7A	0.9600

O1—Ni—N1	88.14 (6)	N3—C8—H8A	109.5
O1—Ni—N2ⁱ	88.87 (6)	N3—C8—H8B	109.5
N1—Ni—N2ⁱ	88.32 (7)	H8A—C8—H8B	109.5
O1—Ni—Cl1	171.70 (4)	N3—C8—H8C	109.5
N1—Ni—Cl1	96.57 (5)	H8A—C8—H8C	109.5
N2ⁱ—Ni—Cl1	84.46 (5)	H8B—C8—H8C	109.5
O1—Ni—Cl2	93.85 (4)	O2—C9—N4	126.7 (2)
N1—Ni—Cl2	93.17 (5)	O2—C9—H9A	116.7
N2ⁱ—Ni—Cl2	176.93 (5)	N4—C9—H9A	116.7
Cl1—Ni—Cl2	92.710 (18)	N4—C10—H10A	109.5
O1—Ni—Cl1ⁱⁱ	88.36 (4)	N4—C10—H10B	109.5
N1—Ni—Cl1ⁱⁱ	174.19 (4)	H10A—C10—H10B	109.5
N2ⁱ—Ni—Cl1ⁱⁱ	86.97 (5)	N4—C10—H10C	109.5
Cl1—Ni—Cl1ⁱⁱ	86.372 (17)	H10A—C10—H10C	109.5
Cl2—Ni—Cl1ⁱⁱ	91.690 (18)	H10B—C10—H10C	109.5
N1—C1—C2	122.69 (18)	N4—C11—H11A	109.5
N1—C1—H1A	118.7	N4—C11—H11B	109.5
C2—C1—H1A	118.7	H11A—C11—H11B	109.5
C1—C2—C3	119.24 (19)	N4—C11—H11C	109.5
C1—C2—H2A	120.4	H11A—C11—H11C	109.5
C3—C2—H2A	120.4	H11B—C11—H11C	109.5
C2—C3—C4	118.92 (19)	C5—N1—C1	117.80 (17)
C2—C3—H3A	120.5	C5—N1—Ni	123.02 (13)
C4—C3—H3A	120.5	C1—N1—Ni	119.17 (13)
C3—C4—C5	118.36 (18)	C4—N2—Niⁱⁱⁱ	118.73 (13)
C3—C4—N2	120.29 (18)	C4—N2—H2NA	112.6 (13)
C5—C4—N2	121.23 (18)	Niⁱⁱⁱ—N2—H2NA	97.6 (14)
N1—C5—C4	122.94 (18)	C4—N2—H2NB	112.8 (16)
N1—C5—H5A	118.5	Niⁱⁱⁱ—N2—H2NB	102.9 (16)
C4—C5—H5A	118.5	H2NA—N2—H2NB	111 (2)
O1—C6—N3	123.51 (19)	C6—N3—C7	121.13 (18)
O1—C6—H6A	118.2	C6—N3—C8	120.52 (18)
N3—C6—H6A	118.2	C7—N3—C8	118.24 (17)
N3—C7—H7A	109.5	C9—N4—C10	122.0 (2)
N3—C7—H7B	109.5	C9—N4—C11	120.33 (19)
H7A—C7—H7B	109.5	C10—N4—C11	117.48 (19)
N3—C7—H7C	109.5	C6—O1—Ni	126.39 (13)
H7A—C7—H7C	109.5	Ni—Cl1—Niⁱⁱ	93.628 (17)
H7B—C7—H7C	109.5