Table 5.
Binding and activation volumes in the urease-catalyzed hydrolysis of urea, obtained from pressure-dependent measurements performed at 25 °C
p (MPa) | ΔV b (K M) (mL/mol) |
|
ΔV ≠ (K M/k cat) (mL/mol) |
---|---|---|---|
<40 | −2 ± 2 | 5 ± 1 | 9 ± 4 |
>40 | −2 ± 2 | 28 ± 1 | 26 ± 3 |