Table 5.
Thermodynamic parameters for inversion of 8
| Entry | Description | ΔH‡ (kcal/mol) | ΔS‡ (cal/mol·K) |
|---|---|---|---|
| 1 | No ligand in Et2O | 17.5 ± 0.8 | −2.0 ± 0.06 |
| 2 | 1 equiv TMEDA in Et2O | 16.0 ± 1.3 | −9.6 ± 0.5 |
| 3 | No ligand in THF | 10.1 ± 0.9 | −29.1 ± 4.2 |
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