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. Author manuscript; available in PMC: 2012 Sep 17.
Published in final edited form as: Angew Chem Int Ed Engl. 2009;48(18):3333–3336. doi: 10.1002/anie.200900682

Table 3.

Grignard additions to α-aminoxylated cyclohexanone.[a, b]

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[a]

cis configuration and dr determined by 1H NMR.

[b]

Isolated yield of two diastereomers. Based on aminoxylated cyclohexanone.

[c]

RMgBr used in the absence of CeCl3·2LiCl.

[d]

n-BuMgCl used in the absence of CeCl3·2LiCl.

[e]

RLi used instead of RMgCl.