Table 1.
MCA values for N-centered Lewis bases, ordered by increasing MCA values.
| system | MCA [kJ/mol] | system | MCA [kJ/mol] |
| NH3 (2) | +436.5 | NH2Me (3) | +488.7 |
| NMePh2 (4) | +514.4 | pyridine (1) | +518.7 |
| Nc-Pr3 (5) | +521.2 |
 (6) |
+521.4 |
| NHMe2 (7) | +523.1 | NMec-Pr2 (8) | +523.7 |
| NMe2Ph (9) | +527.7 |
 (10) |
+529.4 |
 (11) |
+531.1 |
 (12) |
+531.7a |
| NMe2c-Pr (13) | +532.0 |
 (14) |
+532.8 |
 (15) |
+535.9 | N(iPr)3 (16) | +536.0 |
 (17) |
+538.2 |
 (18) |
+539.8 |
 (19) |
+541.5 | NMe3 (20) | +543.5 |
| Nt-Bu3 (21) | +545.5 | NMe2Et (22) | +548.6 |
| NMet-Bu2 (23) | +549.4 |
 (24) |
+550.0 |
| NMe2c-Bu (25) | +551.2 | NMe2(iPr) (26) | +551.7 |
| NMe2n-Pr (27) | +552.1 |
 (28) |
+552.5 |
| NMe2t-Bu (29) | +552.6 | NMe2n-Bu (30) | +553.8 |
| NMe2c-Pen (31) | +554.3 | NMe2n-Pen (32) | +554.5 |
| NMe2c-Oct (33) | +554.6 |
 (34) |
+555.2 |
| NMeEt2 (35) | +555.3 | NMe2n-Hex (36) | +555.4 |
| NMe2n-Hep (37) | +555.7 | Nc-Hex3 (38) | +556.9 |
| NMe(iPr)2 (39) | +557.3 | NMe2c-Hep (40) | +560.3 |
| NMec-Bu2 (41) | +560.4 | NMe2c-Hex (42) | +561.1 |
| NMen-Pr2 (43) | +561.7 |
 (44) |
+562.2 |
| NEt3 (45) | +562.3 | NMen-Bu2 (46) | +564.1 |
| Nn-Pr3 (47) | +567.5 | Nc-Pen3 (48) | +568.3 |
| NMec-Pen2 (49) | +570.6 | Nc-Bu3 (50) | +570.9 |
| NMec-Hex2 (51) | +572.0 |
 (52) |
+576.0 |
 (53) |
+580.6 |
 (54) |
+581.2b |
| NPh3 (55) | +583.5 |
 (56) |
+590.1b |
 (57) |
+602.7 |
 (58) |
+609.0 |
 (59) |
+609.1 |
 (60) |
+609.6c |
 (61) |
+611.0 |
 (62) |
+613.3 |
 (63) |
+616.0 |
 (64) |
+620.8 |
 (65) |
+624.1b,d | ||
aN3; bpyridine nitrogen; cN(sp²); dsee [7].