Table 2.
MCA values of saturated trialkylphosphanes without heteroatoms, PPh3, PH3, PH2Me and PHMe2, ordered by increasing MCA values.
| system | MCA [kJ/mol] | system | MCA [kJ/mol] |
| PH3 (66) | +448.4 | PH2Me (67) | +513.0 |
| PHMe2 (68) | +564.2 |
 (69) |
+603.3 |
| PMe3 (70) | +604.2 |
 (71) |
+606.9 |
| Me2c-Pr (72) | +607.2 |
 (73) |
+607.9 |
| PMe2Et (74) | +610.5 | Mec-Pr2 (75) | +611.8 |
 (76) |
+611.9 | PMe2(iPr) (77) | +613.5 |
| PMe2n-Pr (78) | +614.3 | PMeEt2 (79) | +616.1 |
| PMe2n-Bu (80) | +616.3 | PMe2c-Bu (81) | +616.7 |
| PMe2n-Pen (82) | +617.3 |
 (83) |
+617.3 |
| PMe2n-Hex (84) | +617.7 | PMe2n-Hep (85) | +617.9 |
| PMe2n-Oct (86) | +618.1 |
 (87) |
+618.2. |
 (88) |
+618.5 | PPh3 (89) | +618.7 |
 (90) |
+618.8 | PMe2t-Bu (91) | +619.4 |
 (92) |
+619.5 |
 (93) |
+619.6 |
| PMe2c-Pen (94) | +620.4 |
 (95) |
+620.8 |
| Pc-Pr3 (96) | +621.1 | PMe2c-Hex (97) | +621.9 |
| PEt3 (98) | +622.5 |
 (99) |
+623.3 |
| PMen-Pr2 (100) | +624.1 |
 (101) |
+624.5 |
| PPh2n-Bu (102) | +624.6 | PMe(iPr)2 (103) | +624.8 |
| PMe2c-Hep (104) | +624.9 |
 (105) |
+625.7 |
| PMe2c-Oct (106) | +626.1 | PMe2c-Non (107) | +627.5 |
 (108) |
+627.7 | PMen-Bu2 (109) | +627.8 |
| PMec-Bu2 (110) | +628.7 | PMe2c-Dec (111) | +628.9 |
 (112) |
+630.5 |
 (113) |
+631.7 |
 (114) |
+631.8 | Pn-Pr3 (115) | +633.6 |
| PMet-Bu2 (116) | +635.1 | P(iPr)3 (117) | +635.4 |
| PMec-Pen2 (118) | +637.1 | Pc-Bu3 (119) | +638.5 |
| Pn-Bu3 (120) | +639.5 | PMec-Hex2 (121) | +641.0 |
| Pt-Bu3 (122) | +648.3 | Pc-Pen3 (123) | +650.8 |
| Pc-Hex3 (124) | +655.7 | ||