Table 3.
MCA values of phosphanes containing one to three P–N bonds, ordered by increasing MCA values.
| system | MCA [kJ/mol] | system | MCA [kJ/mol] |
 (125) |
+418.4 |
 (126) |
+451.3 |
 (127) |
+466.1 |
 (128) |
+487.0 |
 (129) |
+523.3 |
 (130) |
+524.6 |
 (131) |
+535.5 |
 (132) |
+541.2 |
 (133) |
+563.8 |
 (134) |
+605.4 |
 (135) |
+611.9 | Me2P–NMe2 (136) | +615.5 |
 (137) |
+620.0 | Me2P–NMeEt (138) | +620.6 |
 (139) |
+624.7 |
 (140) |
+624.8 |
 (141) |
+626.8 | Me2P–NEt2 (142) | +626.8 |
 (143) |
+626.9 | Me2P–NEtPr (144) | +627.7 |
 (145) |
+629.6 | Me2P–NPr2 (146) | +629.8 |
| MeP(NMe2)2 (147) | +631.8 |
 (148) |
+634.2 |
| P(NMe2)3 (149) | +642.3 |
 (150) |
+642.7 |
| MeP(NMeEt)2 (151) | +642.7 |
 (152) |
+648.7 |
| MeP(NEt2)2 (153) | +653.2 |
 (154) |
+661.6 |
 (155) |
+666.4 |
 (156) |
+666.5 |
 (157) |
+686.6 |
 (158) |
+701.1 |